Synthetic Zeolites – Basic Points

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Having discovered catalytic properties of zeolites in the late 50s intensive studies of their structure, properties and methods of preparation began.
In nature, zeolites are formed by hydrothermal synthesis. Unfortunately effective ways to enrich the rocks aren’t available now, so in practice only rich deposits of zeolites are used.

In the industrial scale, synthetic zeolites are mainly used. Although now more than 30 kinds of natural zeolites, are known, but only 8 of them, found mainly in sedimentary rocks can have the industrial significance. It’s because of certain difficulties associated with the exploration, research and development in this field. In general, throughout the world potential reserves of usable zeolites are large enough.

The level of modern industrial production of synthetic zeolites has reached several hundred thousand tons per year and it is mainly determined by the needs of the petrochemical industry, where some synthetic zeolites are widely used as catalysts or their carriers. Also, zeolites are widely used in drying, purification and separation of substances, as well as ion exchangers.

However, zeolites are considered to be rather interesting objects for scientific research. They have a porous structure with numerous cavities. An important feature of zeolites is the possibility of changing the chemical composition of the crystals and geometrical parameters such as shape and size. This mineral can undergo the structural and chemical modification that can be conducted either by varying the conditions of direct synthesis of zeolites or altering the chemical composition of zeolite crystals of the same structural type.

Due to the relative simplicity of the chemical modification of zeolites there are ample opportunities for the implementation of controlled changes in the structure and properties of crystals. This peculiarity circumstance makes zeolites to be very convenient objects for the study of the nature of adsorption interactions, mechanism and kinetics of catalytic reactions, molecular – sieve effects, molecular diffusion in thin pores of controlled sizes.

As for the prospects of increasing practical use of zeolites I can refer you to the correspondent scientific literature. For example the number of patents on the synthesis and application of zeolites in the US even in 1973 was over 2000, while the number of scientific articles on zeolites, published by the same time. approached to more than 7000.

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